Ruthenium Catalysed Synthesis of Unsaturated Acetals and Aldehydes via C-C Bond Coupling of Alkynes with Allyl Alcohol

DOI: 10.1039/c39940002551

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2551 - 2552 (1994)

Update date:2022-08-17

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Authors:

Derien, Sylvie

Dixneuf, Pierre H.

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Article abstract of DOI:10.1039/c39940002551

Terminal alkynes and allyl alcohol are coupled, with carbon-carbon bond formation, in the presence of a Ru^IV(C5Me5) catalyst, to give γ,δ-unsaturated acetals and with <4> or preferentially to produce the branched γ,δ-unsaturated aldehydes.

Full text of DOI:10.1039/c39940002551

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