A facile generation of organosamarium η3-allyl complexes by reductive cleavage of allylic ethers with (C5Me5)2Sm(THF)n

DOI: 10.1016/0040-4039(95)00071-J

Source and publish data:

Tetrahedron Letters p. 1505 - 1508 (1995)

Update date:2022-08-30

Topics:

Authors:

Takaki, Ken

Kusudo, Takeshi

Uebori, Shinya

Makioka, Yoshikazu

Taniguchi, Yuki

Fujiwara, Yuzo

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Article abstract of DOI:10.1016/0040-4039(95)00071-J

Reductive C-O bond cleavage of allylic benzyl ethers with two equivalents of (C₅Me₅)₂Sm(THF)_n (n=2 or 0) takes place selectively to generate (C₅Me₅)₂Sm(η³-allyl) compl

Full text of DOI:10.1016/0040-4039(95)00071-J

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