Journal of Molecular Structure p. 137 - 148 (1980)
Update date:2022-08-10
Topics:
Iqbal, Khalid
Owen, Noel L.
Sheridan, John
Rotational and centrifugal distortion constants are determined for the ground state and several excited states of the lowest vibrational mode of 1,3-dioxole-2-thione, the "envelope" ring-bending mode.The structure of the molecule is planar.The A-constant is 1percent larger than that of 1,3-dioxole-2-one (vinylene carbonate), which indicates small changes in ring-geometry on substituting C=S for C=O.The dipole moment of 1,3-dioxole-2-thione deduced from Stark-effect measurements is (1.60 +/- 0.02)*E-29 Cm (4.81 +/- 0.06 D).IR and Raman spectra lead to a complete analysis of the normal modes of vibration, based partially on a normal coordinate calculation.
View MoreAlpha(shijiazhuang) Chemical Co., Ltd
Contact:+86-311-85652680
Address:Shijiazhuang City ,Hebei Province China
DANYANG ZHONGTAI TRADE CO .,LTD.
Contact:0086-511-86985511
Address:No.25,Dongfang Rd., Danyang City.Jiangsu P.R.China
website:http://www.sincerityenterp.com
Contact:+86-571-88111846
Address:Binjiang Area, Hangzhou
website:http://www.oceanchem-group.com
Contact:86-536-8596048
Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China
shijiazhuang alkay chemicals co..ltd
Contact:86-311-67692035
Address:2601,juntang building,qiaodong district,shijiazhuang
Doi:10.1021/ic980937p
(1999)Doi:10.1002/chem.201902382
(2019)Doi:10.1016/S0040-4039(00)86760-X
(1982)Doi:10.1246/bcsj.66.3030
(1993)Doi:10.1016/bs.mie.2020.04.060
(2020)Doi:10.1080/00397911.2016.1257724
(2017)