Methylation of bis(oxazolinyl)pyridinerhodium(III) chlorides with trimethylaluminum

DOI: 10.1016/0022-328X(92)80120-M

Source and publish data:

Journal of Organometallic Chemistry p. 227 - 231 (1992)

Update date:2022-08-16

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Authors:

Nishiyama, Hisao

Hirai, Tsuyoshi

Itoh, Kenji

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Article abstract of DOI:10.1016/0022-328X(92)80120-M

Treatment of bis(oxazolinyl)pyridinerhodium(III) trichloride (1) with trimethylaluminium gave the corresponding stable methylrhodium complexes, the mono axial-methyl complex (2) and the cis-dimethyl complex (3), stereoselectively.It is also found that the

Full text of DOI:10.1016/0022-328X(92)80120-M

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