Photochemistry of 1-Azatriptycene

DOI: 10.1021/ja00291a037

Source and publish data:

Journal of the American Chemical Society p. 1329 - 1339 (1985)

Update date:2022-08-11

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Authors:

Sugawara, Tadashi

Iwamura, Hiizu

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Article abstract of DOI:10.1021/ja00291a037

1-Azatriptycene (1) underwent photorearrangement in basic methanol with a quantum efficiency of 0.57 to give 4H-azepine derivative (4) as the main product.In the presence of TCNE, the Diels-Alder adduct (5) of the 1H-azepine intermediate was obtained.In a

Full text of DOI:10.1021/ja00291a037

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