Intramolecular trapping of an ylide intermediate in the reaction of1:CH2 with an allylic alcohol

DOI: 10.1016/0040-4039(95)00532-H

Source and publish data:

Tetrahedron Letters p. 3315 - 3316 (1995)

Update date:2022-08-11

Topics:

Authors:

Sobery, Warunee

DeLuca, Joann P.

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Article abstract of DOI:10.1016/0040-4039(95)00532-H

The reaction of ¹:CH₂, generated by the photolysis of CH₂N₂, with 2-methyl-3-buten-2-ol leads to the formation of several products including 4-methyl-3-penten-1-ol. This product is best explained as the result of rearrangement of an ylide intermediate.

Full text of DOI:10.1016/0040-4039(95)00532-H

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