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to swell for about half an hour. Then styrene (11 ml, 100 mmol)
and ethyl diazo acetate (1.0 ml, 10 mmol) were added and the
solution was heated at 40 °C. 1H NMR spectra of aliquots from
the reaction mixture were recorded at regular intervals. After com-
pletion of the first cycle, evidenced by the complete disappearance
of EDA, the reaction mixture was centrifuged and washed well
with diethyl ether. The residue was utilized for the second cycle
by adding fresh lots of styrene and EDA as mentioned above. The
reaction progress was followed in a similar fashion.
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Acknowledgements
We wish to thank CSIR and DST, New Delhi for financial support
and DST, Delhi for funding the 400 MHz Bruker NMR spectrometer
through the FIST program.
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