
Tetrahedron Letters p. 1857 - 1858 (1997)
Update date:2022-08-30
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Antkowiak, Roza
Antkowiak, Wieslaw Z.
5,6-Dichloro-5,6-dihydro-1,10-phenanthroline (2) was found as an additional product of the hypochlorous acid action on 1,10-phenanthroline. When treated with MCPBA the product of the chlorine addition yielded a corresponding di-N-oxide 3, which readily lost hydrogen chloride under the influence of sodium isopropoxide. The resulting monochloro di-N-oxide 5 molecules (assumed to be flat) revealed a satisfactory stability unless the neutral or basic solution was made acidic.
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(1941)