International Journal of Chemical Kinetics p. 249 - 263 (1993)
Update date:2022-08-10
Topics:
Heberger
Fischer
Absolute rate constants for the addition of the 2-cyano-2-propyl radical to 26 alkenes CH2 = CXY at 315 K were determined in solution by time-resolved electron-spin-resonance spectroscopy. They vary with the alkene substituents from 30 M-1 s-1 to 7′010 M-1 s-1. For styrene the temperature dependence is given by log k/M-1 s-1 = 7.7 - 26.1/Θ where Θ = 2.303 RT in kJ/mol. An analysis of the substituent effects in terms of polar and enthalpic factors reveals a dominant influence of the overall reaction enthalpy.
View More
website:http://www.shochem.com
Contact:021-50800795
Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)
Contact:+86-571-87046953
Address:No. 37, Qingchun Road
Contact:+86-20-32051076
Address:1105,Building A, International Business Incubator,Science City
Jiangyin Tenghua Import&Export Co.,Ltd.
Contact:+86-510-86263875
Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
website:http://www.shochem.com
Contact:021-50800795
Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
Doi:10.1002/chem.200304945
(2004)Doi:10.1007/s43440-021-00221-7
(2021)Doi:10.1021/acs.jpca.0c03987
(2020)Doi:10.1021/bi00689a007
(1975)Doi:10.1016/j.ejmech.2015.02.007
(2015)Doi:10.1021/j100110a019
(1993)
