Pre-isoflavonoid Stages in the Biosynthesis of Amorphigenin: Ring-D Formation and Ring-A Migration

DOI: 10.1039/C39860001063

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1063 - 1065 (1986)

Update date:2022-08-11

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Authors:

Crombi, Leslie

Holden, Ian

Bruggen, Nicholas Van

Whiting, Donald A.

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Article abstract of DOI:10.1039/C39860001063

Despite low incorporations of doubly labelled <13C>acetate during the biosynthesis of amorphigenin by Amorpha fruticosa seedlings, it has been possible to solve the ring-D folding by an INADEQUATE n.m.r. experiment; new proposals are made for the mechanism of the enzyme catalysed flavanone-isoflavone transformation step.

Full text of DOI:10.1039/C39860001063

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