Journal of Molecular Structure p. 217 - 228 (1987)
Update date:2022-08-16
Topics:
Maury, Catherine
Bonniol, Alain
Lere-Porte, Jean-Pierre
Petrissans, Jean
Methylene bending mode analysis (1400-1500 cm-1 region) and dipole moment determinations are carried out in the dissolved state (solvent CCl4) for fluoropropanone (I) and 1,3-difluoropropanone (II).The results are consistent with the existence of two conformations, "cis" and "trans", for (I) and one conformation "cis-trans" for (II).Theoretical evaluations of conformer stabilities by the PCILO method and Onsager formalism are in reasonable agreement with these experimental results.
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