Journal of Fluorine Chemistry p. 99 - 105 (2013)
Update date:2022-08-17
Topics:
Prakash, G. K. Surya
Paknia, Farzaneh
Narayan, Arjun
Mathew, Thomas
Olah, George A.
The one pot synthesis of perimidine and 1,5-benzodiazepine derivatives via condensation of aryldiamines with ketones in the presence of BF 3-H2O is described. BF3-H2O plays a dual role, as an efficient non-oxidizing Br?nsted acid catalyst as well as an effective solvent making the reaction more economic and environmentally safer. The reaction is simple, fast and convenient.
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(2020)Doi:10.1039/c5cc03102h
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