Journal of Physical Chemistry p. 16 - 18 (1988)
Update date:2022-08-11
Topics:
Lavabre, D.
Levy, G.
Laplante, J. P.
Micheau, J. C.
Hysteresis and bistability were observed when a solution of triphenylimidazolyl radical dimer (TPID) is irradiated in a CSTR.The reactor is open to a flow of TPID and irradiated at 360 nm.The transition between the two stable states can be induced by changing either the flow rate or the incoming light flux.This bistability is believed to be the first experimental observation of a genuine chemical instability in an isothermal photochemical system.
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