Tetrahedron Letters p. 5407 - 5410 (1997)
Update date:2022-08-17
Topics:
Fleming, Steven A.
Gao, J. Jerry
Diphenyloxetane was synthesized from photocycloaddition of benzaldehyde and styrene. The oxetane products, 2,3 trans and 2,3 cis isomers, were observed in a 3:1 ratio. Irradiation of 1-phenylpropene and trimethylsilyl cinnamyl ether under the same conditions also gave oxetanes. The silyl group resulted in high stereoselectivity for the oxetane formation.
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