NAD(P+/NAD(P)H models. 83. Molecular asymmetry with a carbonyl group: Electronically controlled stereochemistry in the reaction of NAD(P)+/NAD(P)H analogs

Article abstract of DOI:10.1021/ja00097a021

The N-methylpyridinium salt of 6,7-dihydro-6-methyl-5-oxopyridino[3,2-d]-2-benzazepin has been synthesized. The salt has axial chirality with respect to the orientation of the carbonyl dipole. An enantiomer of the cation has been obtained as the iodide sa