Catalysis Today p. 282 - 290 (2021)
Update date:2022-08-29
Topics:
Yong, Yang
Huajun, Gu
Qingxiao, Zhang
Fang, Zhang
Hui, Li
In this paper, hollow Ni ? P nanospheres (NSs) are prepared through Ni electroless plating on the Au-activated silica NSs externally covered by aminopropyl moieties, followed by removing the silica template with sodium hydroxide. With various characterizations, the resulting hollow Ni ? P NSs are identified to be amorphous alloy. During liquid-phase hydrogenation of sugars to sugar alcohols, the hollow Ni ? P amorphous alloy NSs delivered much superior catalytic performances to the commercial Raney Ni catalyst, showing a good potential in practical applications. Of particular interest is the unique hollow chamber structure of the hollow Ni ? P amorphous alloy NSs, which allows for improving catalytic activity and durability relative to those associated with the dense Ni ? P amorphous alloy NSs. This work demonstrated that such hollow Ni materials with nanoporous chamber structure displayed advantages such as easy experimental handling and high accessibility for the reactants in liquid-phase reaction, more Ni active sites, as well as the existence of more electron-enriched inner surface, which is essential to provide highly efficient catalysts for some reactions.
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Doi:10.1016/S0928-0987(00)00094-4
(2000)Doi:10.1021/ja01416a014
(1926)Doi:10.1016/S0040-4039(00)96114-8
(1987)Doi:10.1002/1521-3765(20020703)8:13<2910::AID-CHEM2910>3.0.CO;2-R
(2002)Doi:10.1080/00397910008087073
(2000)Doi:10.1021/jo00392a025
(1987)