PURIFICATION OF 3-ETHOXYCARBONYLQUINUCLIDINE AND ITS CONVERSION TO 3-QUINUCLIDINECARBOXYLIC ACID AND 3-QUINUCLIDINYLMETHANOL

DOI: 10.1007/BF00532080

Source and publish data:

Chemistry of Heterocyclic Compounds p. 1289 - 1292 (1992)

Update date:2022-08-17

Topics:

Authors:

Koikov, L. N.

Lisitsa, E. A.

Alekseeva, N. A.

Turchin, K. F.

Filipenko, T. Ya.

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Article abstract of DOI:10.1007/BF00532080

3-Ethoxycarbonylquinuclidine obtained by the Grob method is a mixture of 3-ethoxycarbonyl-1-azabicyclo<2.2.2>- and, according to 13C NMR data, 5-ethoxycarbonyl-5-azatricyclo<3.2.1.0^2,7>octanes (about 16:2:1). 3-Ethoxy-carbonylquinuclidine was purified by recrystallization of the hydrochloride, hydrolyzed by water to 3-quinuclidinecarboxylic acid, and reduced by LiAlH4 to 3-quinuclidinylmethanol.

Full text of DOI:10.1007/BF00532080

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