Cram selectivity in the reaction of 2-phenylpropanal with alkyllithium reagents: Myth and reality

DOI: 10.1016/S0040-4020(01)89872-0

Source and publish data:

Tetrahedron p. 6813 - 6820 (1992)

Update date:2022-08-28

Topics:

Authors:

Reetz Reetz

Stanchev

Haning Haning

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Article abstract of DOI:10.1016/S0040-4020(01)89872-0

The reaction of racemic 2-phenylpropanal with methyl- and n-butyllithium was studied in detail. Factors such as temperature, solvent, rate of addition, presence of salts, scale-up and source of reagents were carefully examined. Cram-selectivities of 90-94

Full text of DOI:10.1016/S0040-4020(01)89872-0

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