Journal of the Chemical Society. Perkin transactions II p. 685 - 690 (1983)
Update date:2022-08-30
Topics:
Johnson, Peter G.
Littler, John S.
Quick, Geoffrey R.
The oxidation of 2,6-dimethylphenol by acid aqueous vanadium(V) solution has been studied in the presence both of added acetonitrile and of acetic acid.In the case of the former solvent the reaction can be followed by a conventional u.v. spectrophotometer, but the reaction in acetic acid is much faster and a stopped-flow spectrophotometer, constructed of oxidant- and acid inert materials, was also used.Under both conditions the main products were monomeric and dimeric quinones, and the reactions are second order in vanadium(V).Under both conditions there is evidence for the initial formation of a vanadium(V)-phenol complex which is then further attacked by a further vanadium(V) species.The reactions are acid catalysed.
View MoreGlobal United Biotechnology Inc.
Contact:+86-21-61618568
Address:Room 309, Building 6, NO.135, Jinyu Road, Pudong
Dalian RSD International Trade Co.,Ltd.(expird)
Contact:86-22-60875058 58610575
Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Xinjiang Zhongtai Chemical Co., Ltd.
Contact:+86-991-8788172
Address:NO.78 XISHAN RD.URUMQI，CHINA
Shandong Jiulong Hisince Pharmaceutical Co.,Ltd.
Contact:--
Address:Huadian Pioneer Park, Huadian Township, Qihe County, Dezhou City, Shandong, P.R.China
Shanghai Standard Biotech Co., Ltd.
Contact:+86-18502101150
Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China
Doi:10.1039/b416018e
(2005)Doi:10.1007/s10593-017-2102-0
()Doi:10.1016/j.cattod.2015.01.012
(2015)Doi:10.1002/jhet.5570250357
(1988)Doi:10.1007/PL00005580
(1896)Doi:10.1039/f19898503395
()
