Chemistry Letters p. 1375 - 1378 (1994)
Update date:2022-08-17
Topics:
Kuroda, Chiaki
Mitsumata, Naoko
An acylative C(3)-C(4)-bond cleavage of 4,5-disubstituted 2-trimethylsilylmethyl-penta-2,4-dienoate occurred by treatment with trifluoromethanesulfonic acid in nitriles, while a self-cyclization giving an α-methylene-γ-lactone also occurred when the reactions were carried out in bulky nitriles.
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