Tetrahedron Letters p. 6411 - 6414 (1992)
Update date:2022-08-10
Topics:
Keinan, Ehud
Sinha, Subhash C.
Sinha-Bagchi, Anjana
Wang, Zhi-Min
Zhang, Xiu-Lian
Sharpless, K. Barry
(+)-Disparlure, the sex attractant emitted by the female gypsy moth, Porthetria dispar (L.), and its (-)-enantiomer were synthesized in 43percent yield and >99percent ee, starting from undecanal and using the asymmetric dihydroxylation (AD) reaction.Similarly, the two trans-isomers of disparlure were synthesized in 51percent yield and 95percent ee.
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