Tetrahedron Letters p. 9815 - 9818 (1998)
Update date:2022-08-11
Topics:
Cohen, Shlomo
Zoran, Ami
Sasson, Yoel
The Hoffman degradation reaction is proposed as an unequivocal proof for the validity of the extraction mechanism in Phase Transfer Catalysis (PTC) in the presence of solid NaOH. 4-Chlorobutyronitrile is found to yield cyclopropyl cyanide via an extraction route while 4-bromobutyronitrile reacts to form the same product by the prevalent interfacial mechanism.
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