Mercury in Organic Chemistry. 28. Synthesis of (?-Allyl)palladium Compounds by Remote Palladium Migration

DOI: 10.1021/jo00189a009

Source and publish data:

Journal of Organic Chemistry p. 2701 - 2705 (1984)

Update date:2022-08-11

Topics:

Authors:

Larock, Richard C.

Takagi, Kentaro

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Article abstract of DOI:10.1021/jo00189a009

A variety of organomercurials react regioselectively with 1,4-, 1,5-, 1,6-, and 1,7-dienes and Li2PdCl4 to form good yields of (?-allyl)palladium compounds.These reactions apparently proceed by organopalladium addition to one of the diene double bonds and subsequent palladium migration.

Full text of DOI:10.1021/jo00189a009

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