Bulletin of the Chemical Society of Japan p. 229 - 234 (1986)
Update date:2022-08-15
Topics:
Araki, Koji
Shiraishi, Shinsaku
D-fructose is susceptible to photochemically-induced oxidation by atmospheric oxygen in the presence of a catalytic amount of iron or manganese cations in a neutral to weakly basic pH range.Metal hydroxide does not precipitate from a solution in this pH range because of the high sequestering ability of D-fructose.Upon irradiation of Pyrex-filtered light, D-fructose degraded into D-erythrose and other fragments.This reaction is shown to proceed by coupling with an oxidation-reduction cycle involving a metal cation, i.e., the photooxidation of D-fructose by M(III) and the subsequent reoxidation of the resultant M(II) by atmospheric oxygen.
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