Theoretical Prediction and Experimental Confirmation of Relative Stabilities of Isomeric Allyl Anions from Enamines and Vinyl Ethers

DOI: 10.1039/P29840002019

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Journal of the Chemical Society. Perkin transactions II p. 2019 - 2022 (1984)

Update date:2022-08-29

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Authors:

Inagaki, Satoshi

Iwase, Koji

Goto, Naomi

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Article abstract of DOI:10.1039/P29840002019

Relative stabilities of isomeric allyl anions from enamines and vinyl ethers are predicted in terms of the continuity-discontinuity of the orbital phase.The predictions are supported by ab initio molecular orbital calculations and confirmed by experiments on model compounds.

Full text of DOI:10.1039/P29840002019

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