Journal of Physical Chemistry p. 1867 - 1872 (1995)
Update date:2022-08-11
Topics:
Caminati, Walther
Danieli, Roberto
Dakkouri, Marwan
Bitschenauer, Ralf
The microwave spectrum of (cyclopropylmethyl)acetylene (a newly prepared compound) was investigated in the frequency range 28-40 GHz.Both gauche and cis conformers were observed, the latter being 64 +/- 30 cm-1 lower in energy.The geometries of these conformers were obtained combining the ab initio and microwave spectroscopy results.A large-amplitude motion (the methylacetylene group torsion) was studied by assigning the rotational spectra of several torsionally excited states.
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