Surface Science p. L402 - L406 (1991)
Update date:2022-08-11
Topics:
Hoffmann, F. M.
Weisel, M. D.
In situ Fourier transform infrared reflection absorption spectroscopy reveals the formation of a formate intermediate during the CO hydrogenation reaction at high pressures over a potassium promoted Ru(001) surface. The vibrational data indicate bond formation between potassium and formate. The present results suggest a dual function of alkali promoters in this reaction -- promotion of CO bond dissociation and direct participation in the formation of reaction intermediates.
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