Tetrakis(trimethylphosphine)nickel(0)

DOI: 10.1016/0022-328X(88)89106-X

Source and publish data:

Journal of Organometallic Chemistry p. 535 - 542 (1988)

Update date:2022-08-16

Topics:

Authors:

Avent, Anthony G.

Cloke, F. Geoffrey N.

Day, Jeremy P.

Seddon, Elaine A.

Seddon, Kenneth R.

Smedley, Stephen M.

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Article abstract of DOI:10.1016/0022-328X(88)89106-X

The title complex, , has been prepared by metal-vapour synthesis, and characterized by 1H, 13C, 31P, and 61Ni NMR spectroscopy and ultraviolet photoelectron (PE) spectroscopy.The 61Ni NMR spectrum exhibits a quintet <¹J(NiP) 285 Hz>, and the t₂ and e ionization energies occur at 5.60 and 6.52 eV, the lowest yet observed for a nickel(0) complex.

Full text of DOI:10.1016/0022-328X(88)89106-X

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