Tetrahedron Letters p. 4705 - 4708 (1988)
Update date:2022-08-25
Topics:
Oppolzer, Wolfgang
Gaudin, Jean-Marc
Birkinshaw, Timothy N.
Pd(0)-catalyzed cyclizations of (1-acetoxy-3-alkenyl)-2-cycloalkenes 3, 6 and 12 provide bicyclic systems in high diastereo- (5, 8) and enantio-meric (14) purity consistent with a predominant allylpalladium/alkene cis- insertion.
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