PALLADIUM-CATALYZED INTRAMOLECULAR OLEFIN ALLYLATIONS: STEREOCONTROLLED SYNTHESES OF BICYCLIC SYSTEMS AND EVIDENCE FOR AN ALLYLPALLADIUM/OLEFIN-CIS-INSERTION

DOI: 10.1016/S0040-4039(00)80586-9

Source and publish data:

Tetrahedron Letters p. 4705 - 4708 (1988)

Update date:2022-08-25

Topics:

Authors:

Oppolzer, Wolfgang

Gaudin, Jean-Marc

Birkinshaw, Timothy N.

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Article abstract of DOI:10.1016/S0040-4039(00)80586-9

Pd(0)-catalyzed cyclizations of (1-acetoxy-3-alkenyl)-2-cycloalkenes 3, 6 and 12 provide bicyclic systems in high diastereo- (5, 8) and enantio-meric (14) purity consistent with a predominant allylpalladium/alkene cis- insertion.

Full text of DOI:10.1016/S0040-4039(00)80586-9

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