Chemistry Letters p. 1983 - 1986 (1988)
Update date:2022-08-24
Topics:
Fukuzumi, Shunichi
Mochizuki, Seiji
Tanaka, Toshio
Photoreduction of phenacyl halides by an NADH model compound, 10-methylacridan (AcrH2), in MeCN proceeds via photoinduced electron transfer from the singlet excited state of AcrH2 to phenacyl halides without the conribution of radical chain reactions, while the photoreduction by another NADH model compound, 1-benzyl-1,4-dihydronicotinamide (BNAH), proceeds via photoinduced radical chain reactions.The origin of the mechanistic difference between AcrH2 and BNAH has been discussed.
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