Russian Chemical Bulletin p. 356 - 359 (1996)
Update date:2022-08-16
Topics:
Avzyanova
Kabal'nova
Shereshovets
The kinetic regularities of conversion of ozone complexes with several substituted benzenes (ArX = C6H5Me, C6H5Et, C6H5CHMe2, C6H5CMe3, C6H5F, C6H5Cl, m-BrC6H5Me, and C6H5CH2Cl) were studied by spectrophotometry. The rate of consumption of ArX·O3 in a CH2Cl2-ArX solution obeys the kinetic equation W = k0[ArX·O3]+k1[ArX·O 3][ArX]. The values of the rate constants k0 and k1 for the complexes studied were determined at -60÷0°C.
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