Kinetic regularities of conversion of ozone complexes with arenes

Article abstract of DOI:10.1007/BF01433971

The kinetic regularities of conversion of ozone complexes with several substituted benzenes (ArX = C₆H₅Me, C₆H₅Et, C₆H₅CHMe₂, C₆H₅CMe₃, C₆H₅F, C₆H₅Cl, m-BrC₆H₅Me, and C₆H₅CH₂Cl) were studied by spectrophotometry. The rate of consumption of ArX·O₃ in a CH₂Cl₂-ArX solution obeys the kinetic equation W = k₀[ArX·O₃]+k₁[ArX·O ₃][ArX]. The values of the rate constants k₀ and k₁ for the complexes studied were determined at -60÷0°C.