Journal of Organometallic Chemistry p. 95 - 100 (1983)
Update date:2022-08-29
Topics:
Funabiki, Takuzo
Nakamura, Hitoshi
Yoshida, Satohiro
Tetracyanocobaltate(I), which is formed in strongly alkaline solutions of cyanocobaltate under H2 at Cn:Co < 5;1, reacts readily with aryl halides to form ?-arylpentacyanocobaltates(III). 1H and 13C NMR spectra of these new and fairly stable complexes have been determined.In the reactions of some aryl halides, aryl cyanides as well as hydrogenolysis products are formed, and α-bromonaphthalene reacts selectively to give the highest yield of the nitrile.The reactions are explained by a mechanism involving an electron-transfer process.
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