Stereostructural Studies on the 4-Hydroxylated Annonaceous Acetogenins: Synthesis of Model Butenolides of Known Relative and Absolute Configuration Involving an Intriguing Translactonization Reaction

DOI: 10.1016/S0040-4039(00)78427-9

Source and publish data:

Tetrahedron Letters p. 8525 - 8528 (1994)

Update date:2022-08-11

Topics:

Authors:

Hoye, Thomas R.

Hanson, Paul R.

Hasenwinkel, Linda E.

Ramirez, Elizabeth A.

Zhuang, Zhiping

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Article abstract of DOI:10.1016/S0040-4039(00)78427-9

Each diastereomer of model butenolides 3 was synthesized from appropriate antipodes of two propylene oxide molecules.Concomitant translactonization reactions have important stereochemical ramifications.

Full text of DOI:10.1016/S0040-4039(00)78427-9

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