Carbonylation of bromobenzene in a biphasic medium catalysed by water-soluble palladium complexes derived from tris(3-sulphophenyl)phosphine

DOI: 10.1016/0022-328X(94)88182-0

Source and publish data:

Journal of Organometallic Chemistry p. 45 - 52 (1994)

Update date:2022-08-11

Topics:

Authors:

Monteil, Fanny

Kalck, Philippe

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)88182-0

The hydroxycarbonylation of bromobenzene has been explored in a biphasic medium.Water-soluble (TPPTS = sodium salt of tris(3-sulphophenyl) phosphine) catalyses selectively this carbonylation reaction into benzoic acid.This complex is maintained intact in the presence of an excess of tris(3-sulphophenyl)phosphine salt.Even when a hydrogen donor is added, the reaction is limited to hydroxycarbonylation.The two complexes and have been synthesized.A catalytic cycle is proposed.Key words: Palladium; Carbonylation; Biphatic medium Phosphines; Mechanism

Full text of DOI:10.1016/0022-328X(94)88182-0

Products guided by the article

Product name:Benzoic acid

Cas No:65-85-0

R&D Labs maybe for 65-85-0

Exploiter Molybdenum Co.,Ltd

Contact:86-379-63338609

Address:Jiudian Village,Deting Town,Song County,Luoyang
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

website:http://www.czyys.com

Contact:0086-519-88802789

Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China
zhuzhou zhongle chemical co. ltd.

Contact:+86-0731 28228409

Address:Zhuzhou, Hunan, China
Shanghai Zhihua ChemTech Co., Ltd.

Contact:+86-13774313779

Address:Room 817 Suite B 3333 Shenjiang Road

Relevant to this article

Suzuki-Miyaura coupling catalyzed by polymer-incarcerated palladium, a highly active, recoverable, and reusable Pd catalyst

Doi:10.1021/ol049429b
(2004)
Higher Carbon Analogues of 1,4-Dihydropyridines as Potent TGFβ/Smad Inhibitors

Doi:10.1002/ejic.201901223
(2020)
The coordination chemistry of 3,3′-diamino-2,2′-bipyridine and its dication: Exploring the role of the amino groups by x-ray crystallography

Doi:10.1002/1099-0682(200208)2002:8<1985::AID-EJIC1985>3.0.CO;2-G
(2002)
Synthesis, optical, and antioxidant studies of anthraquinone-core-based dendrimers with N-phenylcarbazole as surface group

Doi:10.1071/CH13521
(2014)
Doi:10.1039/c39780000383
(1978)
Studies on active species for selective catalytic reduction of NO on alumina-supported cobalt oxide catalysts

Doi:10.1246/bcsj.71.2331
(1998)

Article Doi