Journal of Organic Chemistry p. 5952 - 5957 (1993)
Update date:2022-08-11
Topics:
Tsuboi, Sadao
Kuroda, Hirofumi
Takatsuka, Satoshi
Fukawa, Takashi
Sakai, Takashi
Utaka, Masanori
DABCO-catalyzed condensations of ethyl 2,3-butadienoate (1a) with aldehydes at -6 to 25 deg C gave 3-hydroxy-2-vinylidenealkanoates 3 in 41-54percent yields.Butyllithium-promoted condensations of 1a with aldehydes at -105 to -70 deg C afforded 3 in 56-67p
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