Perchlorate Esters. 4. Kinetics and Mechanism of the Reactions of Alkyl Perchlorates with N,N-Dimethylanilines in Benzene

DOI: 10.1021/ja00405a037

Source and publish data:

Journal of the American Chemical Society p. 4515 - 4521 (1981)

Update date:2022-08-10

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Authors:

Kevill, Dennis N.

Shen, Betty W.

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Article abstract of DOI:10.1021/ja00405a037

The reactions in benzene of methyl, ethyl, and isopropyl perchlorates with N,N-dimethylanilines, to yield precipitates of the quaternary anilinium perchlorate, proceed with second-order kinetics and exhibit a large negative entropy of activation.At 25.0 d

Full text of DOI:10.1021/ja00405a037

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