
Tetrahedron Letters p. 5013 - 5016 (1984)
Update date:2022-08-10
Topics:
Corey, E. J.
Shih, Chuan
Shih, Neng-Yang
Shimoji, Katsuichi
Homolytic demercuration of the 1,2-dioxolanes 14a and 14b in the presence of oxygen leads preferentially to endoperoxide 17 (both epimers at C*) which upon reduction affords 8-epi-prostaglandin F2α and the C(15)-epimer, a result in accord with a previous mechanistic proposal.
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