THERMOLYSIS OF THE PROPELLANES. MECHANISM FOR THE THERMOLYSIS OF BICYCLOHEXANES.

DOI: 10.1016/S0040-4039(01)81937-7

Source and publish data:

Tetrahedron Letters p. 3481 - 3484 (1981)

Update date:2022-08-12

Topics:

Authors:

Wiberg, Kenneth B.

Matturro, Michael G.

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Article abstract of DOI:10.1016/S0040-4039(01)81937-7

The thermolysis of the <4.2.2>propellene proceeds with good first order kinetics and gives E_a = 46 kcal/mole.The increase in E_a over that for bicycloy<2.2.0>hexane and the <2.2.0>propellane provides evidence for the mechanism of these thermolyses.

Full text of DOI:10.1016/S0040-4039(01)81937-7

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