Tetrahedron p. 2181 - 2184 (1986)
Update date:2022-08-16
Topics:
Lin, Ai Jeng
Theoharides, Anthony D.
Klayman, Daniel L.
Dihydroartemisinin (2), a sodium borohydride reduction product of artemisinin (1), undergoes thermolysis at 190 deg C to give desoxyartemisinin (3) and a preponderant decomposition product (4) consisting of 2 epimers 4a, (2S, 3R, 6S)-2-(3-oxobutyl)-3-methyl-6-<(R)2-propanal>-cyclohexanone, and 4b, (2S, 3R, 6R)-2-(3-oxobutyl)-3-methyl-6-<(R)2-propanal>-cyclohexanone.
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(2013)
