Journal of the American Chemical Society p. 5335 - 5340 (1989)
Update date:2022-08-30
Topics:
Nicolaou, K. C.
Prasad, C. V. C.
Somers, P. K.
Hwang, C.-K.
Activation of 7-endo over 6-exo hydroxy epoxide opening by placement of an electron-rich double bond furthest away from the hydroxyl group leads to a reliable entry into trans- and cis-substituted oxepane systems.The scope and limitations of the method are discussed and extensions to bicyclic systems are presented.
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