Journal of Organic Chemistry p. 1062 - 1067 (1993)
Update date:2022-08-17
Topics:
Gupta, Sandeep
Krasnoff, Stuart B.
Renwick, J. A. A.
Roberts, Donald W.
Steiner, Jorge Rios
Clardy, Jon
The structures of viridoxins A and B, two novel toxins isolated from the mycelial extract of the fungus Metarhizium flavoviride, were established by spectroscopic methods, chemical correlations, and a single-crystal X-ray analysis of viridoxin B.The absolute configuration of the viridoxins was determined by 1H NMR analysis of chiral (R)- and (S)-O-methyl mandelate derivatives of viridoxin A.
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