Substituent Effects on the Photosolvolyses of 2-Chloropropiophenones in 2,2,2-Trifluoroethanol

DOI: 10.1246/cl.1994.2015

Source and publish data:

Chemistry Letters p. 2015 - 2016 (1994)

Update date:2022-08-11

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Authors:

Usui, Satoshi

Nishimoto, Jyunji

Ohkubo, Katsutoshi

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Article abstract of DOI:10.1246/cl.1994.2015

The substituent effects on the product distribution of the photosolvolyses of 2-chloropropiophenones in 2,2,2-trifluoroethanol were investigated.A ?-electron-donating methoxy substituent at p- and m-position enhanced the heterolytic product of the nucleophilic substitution over that of phenyl-rearrangement.

Full text of DOI:10.1246/cl.1994.2015

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