Chemistry Letters p. 2015 - 2016 (1994)
Update date:2022-08-11
Topics:
Usui, Satoshi
Nishimoto, Jyunji
Ohkubo, Katsutoshi
The substituent effects on the product distribution of the photosolvolyses of 2-chloropropiophenones in 2,2,2-trifluoroethanol were investigated.A ?-electron-donating methoxy substituent at p- and m-position enhanced the heterolytic product of the nucleophilic substitution over that of phenyl-rearrangement.
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