Journal of Physical Chemistry p. 3577 - 3581 (1982)
Update date:2022-08-11
Topics:
Frost, D. C.
Lau, W. M.
McDowell, C. A.
Westwood, N. P. C.
A combination of in situ He I photoelectron and quadrupole mass spectroscopy has been used to study monomeric nitrosomethane, the cis and trans isomers, and formaldoxime.In contrast to earlier results it is shown that cis-(CH3NO)2 sequentially gives CH2=NOH and CH3NO upon vaporization.A photoelectron spectrum of the cis dimer was not observed.In addition, a previous spectrum of "monomeric" CH3NO is shown to belong to the trans dimer.The assignments of the measured ionization potentials for these species are supported by semiempirical HAM/3 results.A breakdown of Koopmans' theorem is confirmed for CH3NO by a calculation involving perturbation corrections.
View More
Shanghai Synmedia Chemical Co., Ltd
Contact:+86-21-38681880
Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
website:http://www.jairadhesales.com
Contact:0091-79-26431096
Address:309 Harikrupa Tower,Nr old Sharda Mandir Char Rasta,Ellisbridge
Contact:86-571-87758773
Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China
Hubei Xiangxi Chemical Industry Co.,Ltd
Contact:+86-710-3454830
Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China
Dezhou Longteng Chemical Co., Ltd.
website:http://www.sodium-methoxide.cn/
Contact:0086-18866052283
Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Doi:10.1016/S0022-328X(97)00333-1
(1997)Doi:10.1002/hlca.19830660134
(1983)Doi:10.1039/jr9610002232
(1961)Doi:10.1016/j.tetlet.2015.01.055
(2015)Doi:10.1021/ja01228a049
(1945)Doi:10.1039/b416397d
(2005)
