Journal of Organometallic Chemistry p. 273 - 282 (1983)
Update date:2022-08-10
Topics:
Petit, F.
Masotti, H.
Peiffer, G.
Buono, G.
The dimerisation of propylene in methylpentenes (60percent) at 25 deg C is catalysed by two active cobalt species.The first, HCoL3, issued from the system "Co(Acac)3/HAlEt2/L" in the presence of 1,5-cyclooctadiene, is more active (*30) and selective in 2-methyl-1-pentene (85percent of dimers) than the second, formed from HCo(COD)2.Under low pressures of propylene (3 bar), the fraction of higher oligomers (mainly trimers) increases only up to 40percent.
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