Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1073 - 1075 (1991)
Update date:2022-08-24
Topics:
Skakovskii, E. D.
Ogorodnikova, M. M.
Tychinskaya, L. Yu.
Chuiko, V. A.
Rykov, S. V.
The effect of an external magnetic field on the ratio of the yields of the basic products of photolysis of aqueous solutions of cyclohexanone was investigated by high-resolution NMR spectroscopy.It was shown that the magnetic field does not significantly affect the yield of the products of the reaction with a 0.2 M concentration of the starting ketone, the yield of 5-hexenal decreases, and the yield of caproic acid and the rate of photolysis increase below 0.02 M.The observed effects are explained by association of cyclohexanone with involvement of the HFI mechanism from the theory of "radical pairs".
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