On the reaction of α-chlorocarbenium ions with sulfinylamines

Article abstract of DOI:10.1055/s-1995-3902

Aryl-, and vinyltrichloromethanes 1 are transformed with antimony pentachloride to α,α-dichlorocarbenium salts 2, which react with sulfinylamines 3 to afford nitrilium salts 4 in good yields. In contrast to this preparatively useful reaction, the reaction