Solanum alkaloids, 139: Photolysis of N-chlorospirosolanes

DOI: 10.1002/jlac.199719970741

Source and publish data:

Liebigs Annalen p. 1589 - 1592 (1997)

Update date:2022-08-11

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Authors:

Quyen, Le Thi

Himmelreich, Uwe

Schreiber, Klaus

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Article abstract of DOI:10.1002/jlac.199719970741

UV irradiation of N-chlorosoladulcidine (2) in trifluoroacetic acid, followed by separation and hydrolysis of the obtained 3-O-trifluoroacetates affords (23R)-23-chlorosoladulcidine (5) and 23,23-dichlorosoladulcidine (7). Similar treatment of N-chlorotomatidine (9) affords 23,23-dichloro-22-isotomatidine (12). VCH Verlagsgesellschaft mbH, 1997.

Full text of DOI:10.1002/jlac.199719970741

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