Materials Research Bulletin p. 1101 - 1106 (1988)
Update date:2022-08-25
Topics:
Diot, Michel
El Mail, Rachad
Bastide, Jean-Pierre
Nguyen-Ba-Chanh
A colorimetry study of thallium pentafluorotellurate (IV) indicates a reversible phase transition near 192 K. Powder diffraction analysis has been performed for the high and low-temperature forms. Structural data are: form I (298 K): monoclinic system; a equals 14. 099 angstrom, b equals 6. 510 angstrom c equals 11. 864 angstrom, beta equals 91. 03 degree ; form II (123 K): monoclinic system; a equals 14. 218 angstrom, b equals 8. 825 angstrom, c equals 8. 559 angstrom, beta equals 91. 2 degree . These results are discussed in comparison with the thermodynamic characteristics of the I yields II transition.
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