Phytochemistry p. 585 - 590 (1994)
Update date:2022-08-10
Topics:
McMorris, Trevor C.
Patil, Prakash A.
Chavez, Rodrigo G.
Baker, Michael E.
Clouse, Steven D.
28-Homobrassinolide has been synthesized from stigmasterol in an overall yield of 21percent.The biological activity of 28-homobrassinolide, brassinolide, 24-epibrassinolide, 22S,23S,24-epibrassinolide, and 22S,23S,28-homobrassinolide have been compared in the soybean epicotyl elongation assay.All the steroids except 22S,23S,28-homobrassinolide exhibited a similar biological activity, but the latter compound was substantially less active.There appears to be a correlation between biological activity and overall dimensions of the steroidal side chain.
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