Chemistry Letters p. 683 - 686 (1982)
Update date:2022-08-16
Topics:
Suzuki, Keisuke
Mukaiyama, Teruaki
Stereoselective cyclization of (Z)-(2R,3R,4R)-6-cyclohexyloxy-1,3,4-tribenzyloxy-5-hexen-2-ol (1) promoted by Hg(OCOCF3)2, followed by reductive work up gave the 2-deoxy-α-hexopyranoside derivative almost exclusively.On the other hand, a predominant formation of the β-anomer was achieved by the treatment of 1 with PhSeCl, and the successive deselenation.
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Doi:10.1016/0040-4020(81)80015-4
(1981)Doi:10.1021/jo00139a017
(1982)Doi:10.1016/S0022-328X(00)89118-4
(1982)Doi:10.1016/S0040-4039(00)82241-8
(1988)Doi:10.1021/ja00381a051
(1982)Doi:10.1021/ja01266a068
(1939)
